7. Atoms and Molecules
I. Choose the best
answer.
1. Which of the
following has the smallest mass?
(a)
6.023 × 1023 atoms of He
(b) 1 atom of He
(c) 2 g of He
(d) 1 mole atoms of He.
2. Which of the
following is a triatomic molecule?
(a)
Glucose (b) Helium
(c) Carbon dioxide (d) Hydrogen
3. The volume occupied
by 4.4 g of CO2 at S.T.P _____.
(a)
22.4 litre (b) 2.24 litre
(c) 0.24 litre (d) 0.1 litre.
4. Mass of 1 mole of
Nitrogen atom is:
(a)
28 amu (b) 14 amu
(c) 28 g (d) 14 g
5. Which of the
following represents 1 amu?
(a)
Mass of a C – 12 atom
(b) Mass of a hydrogen atom
(c)
1/12th of the mass of a C – 12 atom
(d) Mass of O – 16 atom
6. Which of the
following statement is incorrect?
(a) One gram of C – 12 contains Avogadro’s number of atoms.
(b) One mole of oxygen
gas contains Avogadro’s number of molecules.
(c) One mole of hydrogen gas contains Avogadro’s number of atoms.
(d) One mole of electrons stands for 6.023 × 1023 electrons.
7. The volume occupied
by 1 mole of a diatomic gas at S.T.P is _____.
(a)
11.2 litre (b) 5.6 litre
(c) 22.4 litre (d) 44.8 litre.
8. In the nucleus of 20Ca40,
there are_______.
(a)
20 protons and 40 neutrons
(b) 20 protons and 20
neutrons
(c) 20 protons and 40
electrons
(d) 40 protons and 20 electrons.
9. The gram molecular
mass of oxygen molecule is:
(a)
16 g (b) 18 g
(c) 32 g (d) 17 g
10. 1 mole of any
substance contains ______ molecules.
(a) 6.023 × 1023 (b) 6.023 × 10-23
(c) 3.0115 × 1023 (d)
12.046 × 1023.
II. Fill in the blanks
1. Atoms of different
elements having Same mass number, but different atomic numbers are called isobars.
2. Atoms of different
elements having the same number of Neutrons
are called isotones.
3. Atoms of one element
can be transmuted into atoms of other elements by Artificial transmutation.
4. The sum of the
numbers of protons and neutrons of an atom is called its Mass number.
5. Relative atomic mass
is otherwise known as Standard
atomic weight.
6. The average atomic
mass of hydrogen is 1.008
amu..
7. If a molecule is made
of similar kind of atoms, then it is called Homo atomic molecule.
8. The number of atoms
present in a molecule is called its Atomicity.
9. One mole of any gas
occupies 22400 ml at S.T.P.
10. Atomicity of
phosphorous is 4.
III. Match the
following.
a. 8 g of O2 |
0.25 moles |
b. 4 g of H2 |
2
moles |
c. 52 g of He |
13
moles |
d. 112 g of N2 |
4
moles |
e. 35.5 g of Cl2 |
0.5 moles |
IV. True or False: (If
false give the correct statement)
1. Two elements
sometimes can form more than one compound.
Answer: True.
2. Noble gases are
Diatomic
Answer:
False.
Correct Statement:
Noble gases are monoatomic
3. The gram atomic mass
of an element has no unit?
Answer: False.
Correct Statement: The gram atomic mass of an element is expressed in the unit
grams.
4. 1 mole of Gold and
Silver contain the same number of atoms?
Answer: True
5. The molar mass of CO2 is
42 g?
Answer: False.
Correct Statement: The molar mass of CO2 is (12 + 32) = 44 g.
V. Assertion and
Reason:
Answer the following
questions using the data given below:
(i) A and R are correct, R explains the A.
(ii) A is correct, R is wrong.
(iii) A is wrong, R is correct.
(iv) A and R are correct, R doesn’t explain A.
1. Assertion:
Atomic mass of aluminium is 27
Reason: An atom of aluminium is 27 times heavier than 1 / 12th of the
mass of the C – 12 atoms.
Answer: (i) A
and R are correct, R explains the A.
2. Assertion: The
Relative Molecular Mass of Chlorine is 35.5 a.m.u.
Reason: The natural abundance of Chlorine isotopes are not equal.
Answer: (i) A
and R are correct, R explains the A.
VI. Short Answer
Questions
1. Define Relative
atomic mass.
Relative
atomic mass of an element is the ratio between the average mass of its isotopes
to 1 / 12th part of the mass of a carbon – 12 atom. It is denoted as An
2. Write the different
types of isotopes of oxygen and its percentage abundance.
Isotopes
of oxygen:
Isotope Mass (amu)
% abundance |
Isotope Mass (amu)
% abundance |
Isotope Mass (amu)
% abundance |
8O16 |
8O16 |
8O16 |
8O17 |
8O17 |
8O17 |
8O18 |
8O18 |
8O18 |
15.9949 |
15.9949 |
15.9949 |
3. Define Atomicity.
The
number of atoms present in the molecule is called atomicity.
4. Give any two examples
for heteroatomic molecules.
Heterodiatomic
molecules.
e.g.,
- HCl
- NaCl.
5. What is Molar volume
of a gas?
The
volume occupied by one mole of any gas at STP is called molar volume. Its value
is equal to 22.4 litre or 22400 ml or 22400 cm³ or 2.24 × 10-2 m³.
6. Find the percentage
of nitrogen in ammonia.
VII. Long Answer
Questions.
1. Calculate the number
of water molecule present in one drop of water which weighs 0.18 g.
2. N2 +
3H2 → 2NH3 (The atomic mass of nitrogen is 14,
and that of hydrogen is 1)
- 1 mole of nitrogen (____ g) + ____.
- 3 moles of hydrogen (____ g) → ____.
- 2 moles of ammonia (____ g).
Answer:
N2 + 3H2 →
2NH3
- 1 mole of N2 = 28 g
- 3 moles of H2 = 6 g
- 2 moles of NH3 = 34 g
⇒ 1 mole of nitrogen (28 g) + 3 moles of hydrogen (6 g) → 2 moles of Ammonia (34 g).
3. Calculate the number
of moles in:
(i) 27 g of Al
(ii) 1.51 × 1023 molecules of NH4Cl
Answer:
4. Give the salient
features of ‘Modern atomic theory’.
Answer:
(i) An atom is no longer indivisible.
(ii) Atoms of the same element may have different atomic mass.
Eg: isotopes 17Cl35, 17Cl37.
(ii) Atoms of different elements may have same atomic masses.
Eg: Isobars 18Ar40, 20Ca40.
(iv) Atoms of one element can be transmuted into atoms of other elements. An
atom is no longer indestructible.
(v) Atoms may not always combine in a simple whole number ratio.
Eg: Glucose C6H12O6 C : H : O = 6 : 12 :
6 or 1 : 2 : 1.
(vi) Atom is the smallest particle that takes part in a chemical reaction.
(vii) The mass of an atom can be converted into energy (E = mc²).
5. Derive the
relationship between Relative molecular mass and Vapour density.
Answer:
Relative Molecular Mass : The ratio of Mass of one molecule of gas or vapour to the mass of one atom of hydrogen.
VIII. HOT Questions
1. Calcium carbonate is
decomposed on heating in the following reaction CaCO3 → CaO +
CO2
Answer:
(i) How many moles of
Calcium carbonate are involved in this reaction?
One
mole
(ii) Calculate the gram
molecular mass of calcium carbonate involved in this reaction.
Gram
molecular mass of CaCO3
= 40 + 12 + 3(16)
= 100 g
(iii) How many moles of
CO2 are there in this equation?
One
mole.
IX. Solve the
following problems.
1. How many grams are
there in the following?
Answer:
Formula = No. of moles (n) × (Gram molecular mass)
(i) 2 moles of hydrogen
molecule, H2
Mass
of 2 moles of H2 molecule
= 2 × 2 = 4 g
(ii) 3 moles of chlorine
molecule, Cl2
Gram
molecular mass of 3 moles of Cl2
= 3 × 71 = 213 g
(iii) 5 moles of sulphur
molecule, S2
Gram
molecular mass of 5 moles of S2
= 5 × 8(32)
= 5 × 256 = 1280 g
(iv) 4 moles of
phosphorous molecule, P4
Gram
molecular mass of 4 moles of P2
= 4 × 4(31)
= 4 × 124 = 496 g
2. Calculate the % of
each element in calcium carbonate. (Atomic mass: C – 12, O – 16, Ca – 40)
Solution:
3. Calculate the % of
oxygen in Al2(SO4)3. (Atomic mass: Al – 12, O
– 16, S – 32)
Solution:
4. Calculate the %
relative abundance of B – 10 and B – 11, if its average atomic mass is 10.804
amu.
Solution: